Vapor-Phase Indium Intercalation in van der Waals Nanofibers of Atomically Thin W6Te6 Wires

• Published in: ACS nano Vol. 17; no. 6; pp. 5561 - 5569
• Main Authors: Natsui, Ryusuke, Shimizu, Hiroshi, Nakanishi, Yusuke, Liu, Zheng, Shimamura, Akito, Hung, Nguyen Tuan, Lin, Yung-Chang, Endo, Takahiko, Pu, Jiang, Kikuchi, Iori, Takenobu, Taishi, Okada, Susumu, Suenaga, Kazu, Saito, Riichiro, Miyata, Yasumitsu
• Format: Journal Article
• Language: English
• Published: American Chemical Society 28.03.2023
• Subjects: angle-resolved polarized Raman spectroscopy; intercalation; transition metal chalcogenide; one-dimensional van der Waals material; nanowire
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.2c10997

One-dimensional (1D) conducting materials are of great interest as potential building blocks for integrated nanocircuits. Ternary 1D transition-metal chalcogenides, consisting of M6X6 wires with intercalated A atoms (M = Mo or W; X = S, Se, or Te; A = alkali or rare metals, etc.), have attracted much attention due to their 1D metallic behavior, superconductivity, and mechanical flexibility. However, the conventional solid-state reaction usually produces micrometer-scale bulk crystals, limiting their potential use as nanoscale conductors. Here we demonstrate a versatile method to fabricate indium (In)-intercalated W6Te6 (In–W6Te6) bundles with a nanoscale thickness. We first prepared micrometer-long, crystalline bundles of van der Waals W6Te6 wires using chemical vapor deposition and intercalated In into the crystal via a vapor-phase reaction. Atomic-resolution electron microscopy revealed that In atoms were surrounded by three adjacent W6Te6 wires. First-principles calculations suggested that their wire-by-wire stacking can transform through postgrowth intercalation. Individual In–W6Te6 bundles exhibited metallic behavior, as theoretically predicted. We further identified the vibrational modes by combining polarized Raman spectroscopy and nonresonant Raman calculations.