Phosphate Ion-Selective Electrode Based on Electrochemically Modified Iron

• Published in: ACS omega Vol. 9; no. 40; pp. 41217 - 41224
• Main Authors: Fan, Ronghua, Zhang, Xiwen, Wu, Jie, Zhang, Luwei, Chen, Weiyun, Yang, Qiaozhi, Zheng, Rui, Zhang, Lifeng, Li, Xin, Xu, Kebin
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 08.10.2024
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.4c02230

The significance of the detection of phosphate ions is immense in the realms of chemistry, biology, medicine, environment, and industry. The detection of phosphate ions is currently mainly reliant on blue molybdenum colorimetry, which is accurate but requires sample pretreatment, intricate operation, and a high price tag. Consequently, it is essential to create a sensor with superior efficiency, precision, straightforward functioning, and instantaneous online detection. This study has designed and created an electrochemical modification based on an iron metal electrode for this purpose. Cyclic voltammetry was used to initially ascertain the potential (−0.57 V) necessary for constant potential electrolysis. Employing a constant potential electrolysis method, the iron oxide and its phosphate were modified onto the surface of the iron electrode to enable reaction with phosphate ions. Scanning electron microscopy and energy dispersive X-ray spectroscopy were used to characterize and analyze the morphology and elemental composition of Fe-PME, elucidating how it responds to phosphate ionation. The two-electrode system was then utilized for the evaluation of the phosphate ion response of Fe-PME at pH 4. Fe-PME’s response to phosphate ions is demonstrated by the results, ranging from 10–5 to 0.1 M and with a slope of −52.8 mV dec–1. Fe-PME exhibited satisfactory results when compared to the conventional blue colorimetry of molybdenum.