Nitrone Synthesis via Pair Electrochemical Coupling of Nitro-Compounds with Benzyl Alcohol Derivatives

Here we report a paired electrochemical coupling of readily accessible nitro-compounds with benzyl alcohols to yield nitrone derivatives. In this work, electrochemical behavior of nitrobenzene and benzyl alcohol derivatives was studied by cyclic voltammetry and controlled potential coulommetry. Elec...

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Bibliographic Details
Published inJournal of organic chemistry Vol. 84; no. 14; pp. 9307 - 9312
Main Authors Salehzadeh, Hamid, Mashhadizadeh, Mohammad Hossein
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 19.07.2019
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
MILD
CYCLOADDITION REACTIONS
ONE-POT SYNTHESIS
N,N-DISUBSTITUTED HYDROXYLAMINES
TERTIARY-AMINES
CATALYTIC-OXIDATION
HYDROGEN-PEROXIDE
STEP SYNTHESIS
SECONDARY-AMINES
EFFICIENT METHOD
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Summary:Here we report a paired electrochemical coupling of readily accessible nitro-compounds with benzyl alcohols to yield nitrone derivatives. In this work, electrochemical behavior of nitrobenzene and benzyl alcohol derivatives was studied by cyclic voltammetry and controlled potential coulommetry. Electrochemical reactions have been performed in aqueous/ethanol (or acetonitrile) solutions by employing common graphite electrodes and a simple controlled current protocol which can make this strategy more appealing than other conventional pathways.
Bibliography:ObjectType-Article-1
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ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.9b00736