Particulate–Droplet Coalescence and Self-Transport on Superhydrophobic Surfaces

• Published in: ACS nano Vol. 16; no. 8; pp. 12910 - 12921
• Main Authors: Yan, Xiao, Ji, Bingqiang, Feng, Lezhou, Wang, Xiong, Yang, Daolong, Rabbi, Kazi Fazle, Peng, Qi, Hoque, Muhammad Jahidul, Jin, Puhang, Bello, Elizabeth, Sett, Soumyadip, Alleyne, Marianne, Cropek, Donald M., Miljkovic, Nenad
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 23.08.2022
• Subjects: Animals; Hydrophobic and Hydrophilic Interactions; Plant Leaves; Water - chemistry; Wettability; Wings, Animal; coalescence; microdroplet; particulate; self-cleaning; superhydrophobic
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.2c05267

Particulate transport from surfaces governs a variety of phenomena including fungal spore dispersal, bioaerosol transmission, and self-cleaning. Here, we report a previously unidentified mechanism governing passive particulate removal from superhydrophobic surfaces, where a particle coalescing with a water droplet (∼10 to ∼100 μm) spontaneously launches. Compared to previously discovered coalescence-induced binary droplet jumping, the reported mechanism represents a more general capillary-inertial dominated transport mode coupled with particle/droplet properties and is typically mediated by rotation in addition to translation. Through wetting and momentum analyses, we show that transport physics depends on particle/droplet density, size, and wettability. The observed mechanism presents a simple and passive pathway to achieve self-cleaning on both artificial as well as biological materials as confirmed here with experiments conducted on butterfly wings, cicada wings, and clover leaves. Our findings provide insights into particle–droplet interaction and spontaneous particulate transport, which may facilitate the development of functional surfaces for medical, optical, thermal, and energy applications.