Kinetic study of .beta.-hydride elimination of monoalkyl complexes of platinum(II): effects of varying the alkyl chain length or the cis group in the reaction of cis-bis(triethylphosphine)(alkyl)(halo or pseudohalo)platinum(II) complexes

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Bibliographic Details
Published inInorganic chemistry Vol. 29; no. 18; pp. 3467 - 3472
Main Authors Alibrandi, Giuseppe, Monsu Scolaro, Luigi, Minniti, Domenico, Romeo, Raffaello
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.09.1990
Subjects
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
Substituent effect
Divalent metal Complexes
Tertiary phosphine
Elimination
Organic ligand
Activation parameter
Transition metal Complexes
Acido complex
Cis stereoisomer
Platinoid Complexes
Rate constant
Thermodynamic properties
NMR spectrum
Platinum II Complexes
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Bibliography:istex:363C5C71F160BBD24762C7BC4555E14A365D45AF
ark:/67375/TPS-CD4BL948-2
ISSN:0020-1669
1520-510X
DOI:10.1021/ic00343a037