Singlet and triplet biradical intermediates in the valence isomerization of 2,7-dihydro-2,2,7,7-tetramethylpyrene

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 115; no. 13; pp. 5400 - 5409
Main Authors Hasler, Erich, Hoermann, Aldo, Persy, Gabriele, Platsch, Herbert, Wirz, Jakob
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.06.1993
Subjects
Chemistry
Exact sciences and technology
General and physical chemistry
Photochemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Reaction intermediate
Optical spectrometry
Valence isomerization
EPR spectrometry
Theoretical study
Singlet state
Configuration interaction
Photochemical reaction
Thermal reaction
Experimental study
Condensed benzenic compound
Pariser Parr Pople method
Fluorescence spectrometry
Triplet state
SCF method
Near ultraviolet radiation
Semiempirical method
Kinetic parameter
Rate constant
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More Information
Bibliography:ark:/67375/TPS-ZWD1LWLX-V
istex:A6239301E1582B721C400EE9FAF3A456E1C3E95B
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00066a007