Coupling Effect of Structural Lubrication and Thermal Excitation on Phononic Friction

• Published in: ACS applied materials & interfaces Vol. 16; no. 19; pp. 25519 - 25528
• Main Authors: Dong, Yun, Yang, Futian, Wang, Jinguang, Tang, Xinyi, Tao, Yi, Shi, Bo, Liu, Yifan
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 15.05.2024
• Subjects: Surfaces, Interfaces, and Applications; black phosphorus; thermal lubrication; thermal collision; phonon spectrum; potential energy period
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.4c01488

This work investigates the coupling effect of structural lubrication and thermal excitation on phononic friction between black phosphorus (BP) layers. As the rotation angle increases from commensurate to incommensurate states, the friction gradually decreases at any temperature. However, the role of temperature in friction depends on commensurability. For a rotation angle less than 10°, increasing temperature leads to a decrease in friction due to thermal excitation. Conversely, when the rotation angle exceeds 10°, elevated temperature results in an increase in friction due to the effect of thermal collision. At a critical rotation angle of 10°, higher temperatures lead to reduced friction through thermal lubrication at low speeds, and at large speeds, the thermal excitation duration becomes so short that the role of thermal lubrication is weakened, and instead thermal collision dominates. Further research reveals that BP’s ability to withstand different maximum speeds is also determined by commensurability. Finally, a method to measure the sliding period length of a rotated tip through an unrotated substrate potential energy topography is proposed and simply verified by using the phonon spectrum.