Bismuth Subcarbonate with Designer Defects for Broad-Spectrum Photocatalytic Nitrogen Fixation

• Published in: ACS applied materials & interfaces Vol. 10; no. 30; pp. 25321 - 25328
• Main Authors: Xu, Chenmin, Qiu, Pengxiang, Li, Liyuan, Chen, Huan, Jiang, Fang, Wang, Xin
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 01.08.2018
• Subjects: photocatalytic nitrogen fixation; bismuth subcarbonate; defect level; controllable defect density; oxygen vacancies
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.8b05925

A facial hydrothermal method is applied to synthesize bismuth subcarbonate (Bi2O2CO3, BOC) with controllable defect density (named BOC-X) using sodium bismuthate (NaBiO3) and graphitic carbon nitride (GCN) as precursors. The defects of BOC-X may originate from the extremely slow decomposition of GCN during the hydrothermal process. The BOC-X with optimal defect density shows a photocatalytic nitrogen fixation amount of 957 μmol L–1 under simulated sunlight irradiation within 4 h, which is 9.4 times as high as that of pristine BOC. This superior photocatalytic performance of BOC-X is attributed to the surface defect sites. These defects in BOC-X contribute to a defect level in the forbidden band, which extends the light-harvest region of the photocatalyst from the ultraviolet to the visible-light region. Besides, surface defects prevent electron–hole recombination by accommodating photogenerated electrons in the defect level to promote the separation efficiency of charge carrier pairs. This work not only demonstrates a novel and scalable strategy to synthesize defective Bi2O2CO3 but also presents a new perspective for the synthesis of photocatalysts with controllable defect density.