The stability of bridgehead and rigid tertiary carbenium ions in the gas phase and their rate of formation in solvolysis reactions

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 114; no. 15; pp. 6169 - 6172
Main Authors Mueller, Paul, Milin, Didier, Feng, Weiging Q, Houriet, Raymond, Della, Ernest W
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.07.1992
Subjects
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Chemical stability
Theoretical study
Bromocarbon
Polycyclic compound
Solvolysis
Sulfonate
Force field method
Carbocation
Gas phase
Rate constant
Thermodynamic properties
Ion cyclotron resonance
Ethylenic compound
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Bibliography:ark:/67375/TPS-6F5JN535-K
istex:52A90CBF71763BDEF5F5B4196AE12EDFDFBBF0C3
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00041a039