Investigation of Ice-Templated Porous Electrodes for Application in Organic Batteries

Application and investigation of porous composite electrodes for organic batteries fabricated by an ice-templating method are reported for the first time. The possibility to produce polymer composite electrodes with highly aligned, parallel pores is demonstrated and electrochemical investigations ar...

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Published inACS applied materials & interfaces Vol. 8; no. 36; pp. 23614 - 23623
Main Authors Stolze, Christian, Janoschka, Tobias, Flauder, Stefan, Müller, Frank A, Hager, Martin D, Schubert, Ulrich S
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 14.09.2016
Subjects
organic batteries
energy storage
porous electrodes
TEMPO
freeze casting
PTMA
ORB
ice-templating
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Summary:Application and investigation of porous composite electrodes for organic batteries fabricated by an ice-templating method are reported for the first time. The possibility to produce polymer composite electrodes with highly aligned, parallel pores is demonstrated and electrochemical investigations are presented to examine their suitability for application in organic batteries. The performance of such ice-templated porous electrodes is experimentally compared with planar electrodes of similar composition against zinc and lithium counter electrodes, respectively. Fundamental properties limiting the performance of ice-templated porous electrodes are discussed and further means to overcome those limitations are proposed.
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ISSN:1944-8244
1944-8252
DOI:10.1021/acsami.6b05018