Poly(aniline boronic acid): A New Precursor to Substituted Poly(aniline)s
A novel strategy for preparing a wide range of substituted poly(aniline)s from a single precursor is described. This approach relies on a boron activation/electrophilic displacement reaction resulting in ipso-substitution. Specifically, we demonstrate this strategy to prepare a few of the many possi...
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Published in | Langmuir Vol. 17; no. 23; pp. 7183 - 7185 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
13.11.2001
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Online Access | Get full text |
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Summary: | A novel strategy for preparing a wide range of substituted poly(aniline)s from a single precursor is described. This approach relies on a boron activation/electrophilic displacement reaction resulting in ipso-substitution. Specifically, we demonstrate this strategy to prepare a few of the many possible structures that can be generated from poly(aniline boronic acid), including poly(hydroxyaniline) and halogenated poly(aniline)s. The ability to tune the properties of poly(aniline) through the generation of these new structures will be useful in diverse fields where poly(aniline) is used ranging from polymer-based electronics to sensors. |
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Bibliography: | istex:E184F2A979C4FEA9C491062A3108F22FE9367886 ark:/67375/TPS-0HP14B1W-F |
ISSN: | 0743-7463 1520-5827 |
DOI: | 10.1021/la0114272 |