Discrimination of sediment provenance in the Yellow Sea: Secondary grain-size effect and REE proxy

• Published in: Journal of Asian earth sciences Vol. 123; pp. 78 - 84
• Main Authors: Jung, Hoi-Soo, Lim, Dhongil, Jeong, Do-Hyun, Xu, Zhaokai, Li, Tiegang
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.06.2016
• Subjects: Quantification; Rare earth elements; Secondary grain-size effect; Sediment provenance; Yellow Sea; Rare earth elements; Quantification; Yellow Sea; Sediment provenance; Secondary grain-size effect
• ISSN: 1367-9120; 1878-5786
• DOI: 10.1016/j.jseaes.2016.03.020

[Display omitted] •REE fractionation patterns were analyzed for river and shelf sediments.•Quantitative contribution of Chinese or Korean rivers to the sea was estimated.•Contribution of sediment sources was mapped for a whole area of the sea.•Depositional process in the Yellow Sea and a new provenance discrimination tool were discussed. This study analyzed grain size and elemental concentrations (Al, Mg, Fe, and rare earth elements (REEs)) in 91 surface sediments to elucidate sediment provenance in the Yellow Sea. Elemental concentrations were normalized by Al concentration (Celement/CAl) to minimize the sediment grain-size effect (GSE). However, noticeable linear relationships between Al concentration (or mean grain size) and the ratio (e.g., Mg/Al or Fe/Al) appeared unexpectedly in pair diagrams. The spatial distribution patterns of Fe/Al and Mg/Al ratios were also similar to the pattern of mean grain size. This implies that the GSE was not removed completely, even after the normalization process. Thus, great care must be taken when applying the ratios of Celement/CAl as a proxy of sediment provenance. To improve provenance discrimination of the sediments in the Yellow Sea, the difference between the REE distribution patterns of Chinese and Korean river sediments, expressed as δ (δ=REE∗(La)−REE∗(Lu)), was calculated, and the spatial distribution patterns of the δ values were mapped. The δ values gradually increased from the western to the eastern part of the Yellow Sea, except for low δ values in the southeastern part of the Yellow Sea. This result indicates that the majority of Chinese and Korean river sediments are accumulating near to their respective coasts, except for a deposit along the southwestern coast of Korea in which a considerable amount of sediment from Chinese rivers has been accumulating.