Green and Large-Scale Preparation of Chiral Metal–Organic Frameworks via Mechanochemistry

It is a significant challenge to construct chiral metal–organic frameworks (CMOFs) by developing a facile and green preparation strategy. In this work, CMOFs were first synthesized via a mechanochemical process by combining a truncated mixed ligand strategy and defect engineering theory. The simple,...

Full description

Saved in:
Bibliographic Details
Published inInorganic chemistry Vol. 61; no. 31; pp. 12190 - 12196
Main Authors Jin, Caiju, Chen, Zijuan, Shi, Shunli, Li, Ying, Liu, Sanmei, Wang, Shuhua, Wang, Hongming, Chen, Chao
Format Journal Article
LanguageEnglish
Published American Chemical Society 08.08.2022
Online AccessGet full text

Cover

More Information
Summary:It is a significant challenge to construct chiral metal–organic frameworks (CMOFs) by developing a facile and green preparation strategy. In this work, CMOFs were first synthesized via a mechanochemical process by combining a truncated mixed ligand strategy and defect engineering theory. The simple, green, and rapid construction strategy could solvent-freely harvest gram-scale CMOFs with a hierarchical micro/mesoporous structure. The as-synthesized CMOFs were evaluated by Aldol asymmetric catalysis and exhibited excellent catalytic performance (conversion was up to 97.1%, the ee value was 44.3%, and the activity was still good after 5 cycles).
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.2c01261