Creating an Ethane Trap in a Ketone-Decorated MOF for One-Step Ethylene Separation from C2 Hydrocarbons

One-step C2H4 purification from a mixture of C2H2/C2H4/C2H6 by physical adsorption separation was realized via creating an ethane trap in MOF NTUniv-63 by the utilization of a ketone-decorated semirigid ligand, which has further been verified by the breakthrough experiment, isosteric heats of adsorp...

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Published inInorganic chemistry Vol. 62; no. 46; pp. 18814 - 18819
Main Authors Zhang, Mingxing, Chen, Meng, Jiang, Junyang, He, Xingge, Zhao, Haitian, Wang, Yu, Liu, Penghui, Dang, Rui, Wang, Su, Wang, Miao, Sun, Tongming, Qin, Guoping, Tang, Yanfeng, Cui, Huihui
Format Journal Article
LanguageEnglish
Published American Chemical Society 20.11.2023
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Summary:One-step C2H4 purification from a mixture of C2H2/C2H4/C2H6 by physical adsorption separation was realized via creating an ethane trap in MOF NTUniv-63 by the utilization of a ketone-decorated semirigid ligand, which has further been verified by the breakthrough experiment, isosteric heats of adsorption (Q st), and Grand Canonical Monte Carlo (GCMC) modeling.
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content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.3c03183