Free-Spin Dominated Magnetocaloric Effect in Dense Gd3+ Double Perovskites

• Published in: Chemistry of materials Vol. 34; no. 7; pp. 3440 - 3450
• Main Authors: Koskelo, EliseAnne C., Liu, Cheng, Mukherjee, Paromita, Kelly, Nicola D., Dutton, Siân E.
• Format: Journal Article
• Language: English
• Published: American Chemical Society 12.04.2022
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/acs.chemmater.2c00261

Frustrated lanthanide oxides with dense magnetic lattices are of fundamental interest for their potential in cryogenic refrigeration due to a large ground state entropy and suppressed ordering temperatures but can often be limited by short-range correlations. Here, we present examples of frustrated fcc oxides, Ba2GdSbO6 and Sr2GdSbO6, and the new site-disordered analogue Ca2GdSbO6 ([CaGd] A [CaSb] B O6), in which the magnetocaloric effect is influenced by minimal superexchange (J 1 ∼ 10 mK). We report on the crystal structures using powder X-ray diffraction and the bulk magnetic properties through low-field susceptibility and isothermal magnetization measurements. The Gd compounds exhibit a magnetic entropy change of up to −15.8 J/K/molGd in a field of 7 T at 2 K, a 20% excess compared to the value of −13.0 J/K/molGd for a standard in magnetic refrigeration, Gd3Ga5O12. Heat capacity measurements indicate a lack of magnetic ordering down to 0.4 K for Ba2GdSbO6 and Sr2GdSbO6, suggesting cooling down through the liquid 4-He regime. A mean-field model is used to elucidate the role of primarily free-spin behavior in the magnetocaloric performance of these compounds in comparison to other top-performing Gd-based oxides. The chemical flexibility of the double perovskites raises the possibility of further enhancement of the magnetocaloric effect in the Gd3+ fcc lattices.