Spin-Crossover Phenomenon in Microcrystals and Nanoparticles of a [Fe(2-mpz)2Ni(CN)4] Two-Dimensional Hofmann-Type Polymer: A Detailed Nano-Topographic Study

The diamagnetic two-dimensional Hofmann-type metal–organic framework [ZnII(2-mpz)2Ni­(CN)4] has been successfully synthesized along with its isostructural hysteretic spin-crossover FeII analogue in the form of both bulk microcrystalline powder and nanoparticles. Detailed atomic force microscopy topo...

Full description

Saved in:
Bibliographic Details
Published inInorganic chemistry Vol. 58; no. 20; pp. 13733 - 13736
Main Authors Polyzou, Christina D, Malina, Ondřej, Tuček, Jiri, Zbořil, Radek, Panagiotou, Nikos, Tasiopoulos, Anastasios J, Boukos, Nikos, Parthenios, John, Kalarakis, Alexandros N, Tangoulis, Vassilis
Format Journal Article
LanguageEnglish
Published American Chemical Society 21.10.2019
Online AccessGet full text

Cover

More Information
Summary:The diamagnetic two-dimensional Hofmann-type metal–organic framework [ZnII(2-mpz)2Ni­(CN)4] has been successfully synthesized along with its isostructural hysteretic spin-crossover FeII analogue in the form of both bulk microcrystalline powder and nanoparticles. Detailed atomic force microscopy topographic study revealed a nanogrowth relationship between the height and length of the nanoparticle.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.9b01405