Nonmetal Redox Kinetics: Mono-, Di-, and Trichloramine Reactions with Cyanide Ion

It is shown that chloramines react with excess CN negative by a Cl positive transfer mechanism to yield ClCN as the product and that only the monochloramine reaction is acid-assisted.

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Bibliographic Details
Published inEnvironmental science & technology Vol. 29; no. 4; pp. 1127 - 1134
Main Authors Schurter, Lynn M, Bachelor, Paula P, Margerum, Dale W
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.04.1995
Subjects
Acids
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Ions
Kinetics
Kinetics and mechanism of reactions
Ammonia
Cyanogen Chlorides
Oxidation reduction
Medium effect
Reaction mechanism
pH
Cyanides
Kinetics
Experimental study
Electrochemical reaction
Inorganic compound
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Summary:It is shown that chloramines react with excess CN negative by a Cl positive transfer mechanism to yield ClCN as the product and that only the monochloramine reaction is acid-assisted.
Bibliography:istex:1E2FF008CE6C7511DB0BBA0DDAAA827655A1BA17
ark:/67375/TPS-BCLK2172-0
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0013-936X
1520-5851
DOI:10.1021/es00004a035