Isobaric Vapor–Liquid Equilibrium for Dimethylsulfoxide with Chloroethanes and Chloroethenes

The vapor–liquid equilibrium (VLE) and boiling point data have been measured at 95.3 kPa for the binary systems of dimethylsulfoxide (DMSO) with 1,2-dichloroethane, 1,1,1-trichloroethane, 1,1,2,2-tetrachloroethane, trichloroethene, and tetrachloroethene using a Swietoslawski-ebulliometer. The experi...

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Bibliographic Details
Published inJournal of chemical and engineering data Vol. 53; no. 2; pp. 374 - 377
Main Authors Radhamma, M, Hsieh, Cheng-Ting, Venkatesu, P, Rao, M. V. Prabhakara, Lee, Ming-Jer, Lin, Ho-mu
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.02.2008
Subjects
Chemistry
Exact sciences and technology
General and physical chemistry
Liquid-vapor equilibria
Phase equilibria
Methyl sulfoxide
Isobar
Thermodynamic model
Chlorocarbon
Liquid vapor equilibrium
Ethylene(chloro)
Phase equilibrium
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Summary:The vapor–liquid equilibrium (VLE) and boiling point data have been measured at 95.3 kPa for the binary systems of dimethylsulfoxide (DMSO) with 1,2-dichloroethane, 1,1,1-trichloroethane, 1,1,2,2-tetrachloroethane, trichloroethene, and tetrachloroethene using a Swietoslawski-ebulliometer. The experimental results are analyzed in terms of intermolecular interactions between constituent molecules. The experimental temperature−composition (T, x) data were correlated with the Wilson, NRTL, and UNIQUAC models.
Bibliography:One of the authors (M.R.M.) is highly thankful to University Grants Commission (UGC), New Delhi, India, for providing a teacher fellowship.
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istex:275AEE7647FE2047A30E27CD7E0AA95D44EE50BB
ISSN:0021-9568
1520-5134
DOI:10.1021/je700408x