Amphiphilic Ferrocene Alcohols as Electroactive Probes in Micellar Solutions and Microemulsions
2-Ferrocenyl-2-decanol (FcOHC10), 2-ferrocenyl-2-tetradecanol (FcOHC14), and 2-ferrocenyl-2-octadecanol (FcOHC18) were synthesized and evaluated as electrochemical probes for the behavior of alcohols in micellar solutions and microemulsions. One-electron oxidations of the ferrocene moieties were nea...
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Published in | Langmuir Vol. 13; no. 14; pp. 3693 - 3699 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
09.07.1997
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Subjects | |
Online Access | Get full text |
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Summary: | 2-Ferrocenyl-2-decanol (FcOHC10), 2-ferrocenyl-2-tetradecanol (FcOHC14), and 2-ferrocenyl-2-octadecanol (FcOHC18) were synthesized and evaluated as electrochemical probes for the behavior of alcohols in micellar solutions and microemulsions. One-electron oxidations of the ferrocene moieties were nearly reversible and controlled by diffusion in microemulsions. The electrode reactions were more complex in micellar solutions and were influenced by diffusion, adsorption onto the electrode, and possibly chemical reactions coupled to electron transfer. Amphiphilic ferrocene alcohols were reasonably informative electrochemical probes in bicontinuous microemulsions made with cationic and anionic surfactants. Apparent diffusion coefficients suggested that the alcohols are distributed between the oil−water interfaces and the oil phase of the microemulsions, with increases in chain length favoring binding at this interface. Little evidence was found for adsorption of any ferrocene alcohols at any electrode−microemulsion interface. In comparison to microemulsions of cationic surfactants, the ferrocene alcohols were more easily and rapidly reduced in an SDS microemulsion. This may be attributed to Coulombic interactions between the ferricinium oxidation product and dodecyl sulfate. |
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Bibliography: | ark:/67375/TPS-S4KLQNDF-S istex:8C8B24D5BEB796CDE8E7DDB09BE8E57084B495DB Abstract published in Advance ACS Abstracts, June 15, 1997. |
ISSN: | 0743-7463 1520-5827 |
DOI: | 10.1021/la962037w |