Multiply Colored Electrochromic Carbazole-Based Polymers

• Published in: Chemistry of materials Vol. 9; no. 7; pp. 1578 - 1587
• Main Authors: Sotzing, Gregory A, Reddinger, Jerry L, Katritzky, Alan R, Soloducho, Jadwiga, Musgrave, Richard, Reynolds, John R, Steel, Peter J
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 16.07.1997
• Subjects: Applied sciences; Exact sciences and technology; Organic polymers; Physicochemistry of polymers; Polymerization; Preparation, kinetics, thermodynamics, mechanism and catalysts; Electronic structure; Nitrogen heterocycle; Carbazole derivatives; Preparation; Electrochromism; Tricyclic compound; Electrochemical polymerization; Condensed benzenic compound
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/cm960630t

We report the synthesis and electrochemical polymerization of a series of bisheterocycle-N-substituted carbazoles. These monomers exhibit low peak oxidation potentials (E p,m) which range from 0.15 to 0.46 V vs Ag/Ag+, indicating facile polymerization. Repeated scan electrochemical polymerization for these monomers proceeds rapidly, relative to carbazole, to form stable electroactive films. Cyclic voltammetry of the polymers indicates that the films are well adhered to the electrode surface and that each of the polymers possess two distinct redox waves. At applied potentials greater than 1.15 V, a third irreversible oxidative process is observed, presumedly due to cross-linking. Optoelectrochemical analysis indicates that these polymers have an electronic bandgap (measured as the onset of the π-to-π* transition) between 2.4 and 2.5 eV. Three distinct colors are achievable by varying the redox state of the polymers suggesting potential use for multiply colored electrochromic displays. For the series of bis(ethylenedioxythiophene)-N-substituted carbazoles, the fully reduced form of the polymers are canary yellow. Upon mild oxidation, the films become green and in the fully oxidized form, blue.