Dolomite dissolution: An alternative diagenetic pathway for the formation of palygorskite clay

• Published in: Sedimentology Vol. 66; no. 5; pp. 1803 - 1824
• Main Authors: Ryan, Brooks H., Kaczmarek, Stephen E., Rivers, John M., Tosca, Nicholas
• Format: Journal Article
• Language: English
• Published: Madrid Wiley Subscription Services, Inc 01.08.2019
• Subjects: Aluminum; Carbonates; Cenozoic; Chemical precipitation; Clay; Clay minerals; Computational fluid dynamics; Cores; Crystals; Diagenesis; Dissolution; Dissolving; Dolomite; Dolostone; Electron microscopy; Eocene; Fibers; Fluids; Magnesium; Mesozoic; Mg2; Minerals; Palaeocene; Palygorskite; replacement; Scanning electron microscopy; Silicon; Smectites
• ISSN: 0037-0746; 1365-3091
• DOI: 10.1111/sed.12559

Palygorskite is a fibrous, magnesium‐bearing clay mineral commonly associated with Late Mesozoic and Early Cenozoic dolomites. The presence of palygorskite is thought to be indicative of warm, alkaline fluids rich in Si, Al and Mg. Palygorskite has been interpreted to form in peritidal diagenetic environments, either as a replacement of detrital smectite clay during a dissolution–precipitation reaction or solid‐state transformation, or as a direct precipitate from solution. Despite a lack of evidence, most diagenetic studies involving these two minerals posit that dolomite and palygorskite form concurrently. Here, petrological evidence is presented from the Umm er Radhuma Formation (Palaeocene–Eocene) in the subsurface of central Qatar for an alternative pathway for palygorskite formation. The Umm er Radhuma is comprised of dolomitized subtidal to peritidal carbonate cycles that are commonly capped by centimetre‐scale beds rich in palygorskite. Thin section, scanning electron microscopy and elemental analyses demonstrate that palygorskite fibres formed on both the outermost surfaces of dissolved euhedral dolomite crystals and within partially to completely dissolved dolomite crystal cores. These observations suggest that dolomite and palygorskite formed sequentially, and support a model by which the release of Mg2+ ions and the buffering of solution pH during dolomite dissolution promote the formation of palygorskite. This new diagenetic model explains the co‐occurrence of palygorskite and dolomite in the rock record, and provides valuable insight into the specific diagenetic conditions under which these minerals may form.