Boron Nitride Nanosheets Functionalized with Fe3O4 and CoFe2O4 Magnetic Nanoparticles for Nanofiltration Applications

• Published in: ACS applied nano materials Vol. 6; no. 13; pp. 12526 - 12536
• Main Authors: Dee, Garret, O’Donoghue, Olivia, Rafferty, Aran, Gannon, Lee, McGuinness, Cormac, Gun’ko, Yurii K.
• Format: Journal Article
• Language: English
• Published: American Chemical Society 14.07.2023
• Subjects: boron nitride; magnetic nanoparticles; water remediation; nanofiltration; nanosheets
• ISSN: 2574-0970; 2574-0970
• DOI: 10.1021/acsanm.3c02375

Nanofiltration (NF) is one of the emerging technologies that is very promising for water purification among many other applications. 2D boron nitride (BN) based nanomaterials are excellent building blocks for NF membranes. In our work, BN nanosheets (BNNS) have been functionalized with magnetic nanoparticles (MNPs) to form BNNS–MNP nanocomposites. It was found that the nanocomposites are stable with the MNPs giving very good coverage with both magnetite and cobalt ferrite MNPs and showing good attachment and stability to sonication. These nanocomposites have been tested for removal of methylene blue (MB) dye and MNPs from water. BNNS–magnetite nanocomposites showed higher removal efficiency of the MB from water than the corresponding pure BNNS, while the BNNS–cobalt ferrite removal efficiency was slightly less than the pure BNNS. The BNNS–cobalt ferrite material was regenerated by burning off the MB and recycled to show the recyclability of this material. The BNNS membranes were tested for filtration of 14 ± 4 nm magnetite MNPs and were found to capture 100% of the nanoparticles with no MNPs left in the filtrate. Thus, we have developed magnetic nanocomposite membranes, which have demonstrated great potential for water remediation. We believe that this research opens up promising ways for production of 2D nanocomposite materials with multiple applications.