Crystal Structures and Magnetic Properties of Nickel Chain Compounds PbM2Ni6Te3O18 (M = Mn, Cd)

The synthesis, crystal structures, and magnetic properties of the pentanary oxides PbM2Ni6Te3O18 (M = Mn and Cd) were investigated. These compounds crystallize in a hexagonal structure with space group P63/m, in which the Ni2+ ions form a zigzag chain along the c axis. From the magnetic susceptibili...

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Published inInorganic chemistry Vol. 54; no. 22; pp. 10725 - 10731
Main Authors Doi, Yoshihiro, Suzuki, Ryo, Hinatsu, Yukio, Kodama, Katsuaki, Igawa, Naoki
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 16.11.2015
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Summary:The synthesis, crystal structures, and magnetic properties of the pentanary oxides PbM2Ni6Te3O18 (M = Mn and Cd) were investigated. These compounds crystallize in a hexagonal structure with space group P63/m, in which the Ni2+ ions form a zigzag chain along the c axis. From the magnetic susceptibility and specific heat measurements, we found that the PbCd2Ni6Te3O18 behaves as a low-dimensional magnet due to the intrachain antiferromagnetic interaction between Ni2+ ions. Both compounds show a long-range antiferromagnetic ordering at 25.7 K (M = Cd) and 86.0 K (Mn). The magnetic structure of PbMn2Ni6Te3O18 determined by neutron diffraction measurements is a collinear antiferromagnetic arrangement of Mn2+ ions in the Mn2O9 dimeric unit and Ni2+ ions in the zigzag chain.
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ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.5b01619