Theory and Practice of Alkyl Phenol Synthesis. tert-Octylphenols

Liquid-phase alkylation of phenol with diisobutylenes was studied in the presence of ion-exchange resin Amberlyst 36 Dry. Thermodynamic characteristics were calculated for the reactions that occur in a reaction system. Kinetics of the alkylation process was studied. The conditions of selective synth...

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Published inIndustrial & engineering chemistry research Vol. 55; no. 37; pp. 9829 - 9839
Main Authors Krymkin, Nikita Yu, Shakun, Vladimir A, Nesterova, Tatyana N, Naumkin, Pavel V, Shuraev, Maxim V
Format Journal Article
LanguageEnglish
Published American Chemical Society 21.09.2016
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Summary:Liquid-phase alkylation of phenol with diisobutylenes was studied in the presence of ion-exchange resin Amberlyst 36 Dry. Thermodynamic characteristics were calculated for the reactions that occur in a reaction system. Kinetics of the alkylation process was studied. The conditions of selective synthesis were recommended for 4-tert-octylphenol. Recommendations on the use of obtained data were given.
ISSN:0888-5885
1520-5045
DOI:10.1021/acs.iecr.6b02067