1,4-Diamination of Cyclic Dienes via a (4 + 3) Cycloaddition of Diaza-allyl Cationic Intermediates

Diaza-(4 + 3) cycloadditions of putative diaza-oxyallyl cationic intermediates and cyclic dienes are reported as a method for the 1,4-diamination of cyclic dienes. This reaction was entirely selective for diamination and provided cycloadducts in good to excellent yield.

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Bibliographic Details
Published inOrganic letters Vol. 14; no. 22; pp. 5764 - 5767
Main Authors Jeffrey, Christopher S, Anumandla, Devendar, Carson, Christopher R
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 16.11.2012
Amer Chemical Soc
Subjects
Alkadienes - chemistry
Amination
Catalysis
Chemistry
Chemistry, Organic
Combinatorial Chemistry Techniques
Cyclization
Molecular Structure
Nuclear Magnetic Resonance, Biomolecular
Physical Sciences
Science & Technology
PALLADIUM
POTENT
GENERATION
DIELS-ALDER REACTIONS
1,3-DIENES
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Summary:Diaza-(4 + 3) cycloadditions of putative diaza-oxyallyl cationic intermediates and cyclic dienes are reported as a method for the 1,4-diamination of cyclic dienes. This reaction was entirely selective for diamination and provided cycloadducts in good to excellent yield.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol302771z