Parallel Carbon Nanotube Stripes in Polymer Thin Film with Remarkable Conductive Anisotropy

• Published in: ACS applied materials & interfaces Vol. 6; no. 3; pp. 1754 - 1758
• Main Authors: Huang, Jinrui, Zhu, Yutian, Jiang, Wei, Yin, Jinghua, Tang, Qingxin, Yang, Xiaodong
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 12.02.2014
• Subjects: thin film; carbon nanotube; shear flow; conductive anisotropy; hierarchical assembly
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/am404758d

In our previous study (Mao et al. J. Phys. Chem. Lett. 2013, 4, 43−47 ), we proposed a novel method, that is, the shear-flow-induced hierarchical self-assembly of two-dimensional fillers (octadecylamine-functionalized graphene) into the well-ordered parallel stripes in a polymer matrix, to fabricate the anisotropic conductive materials. In this study, we extend this method to one-dimensional multiwalled carbon nanotubes (MWCNTs). Under the induction of shear flow, the dispersed poly­(styrene ethylene/butadiene-styrene) (SEBS) phase and MWCNTs can spontaneously assemble into well-ordered parallel stripes in the polypropylene (PP) thin film. The electrical measurements indicate that the electrical resistivity in the direction parallel to the stripes is almost 6 orders of magnitude lower than that in the perpendicular direction, which is by far the most striking conductive anisotropy for the plastic anisotropic conductive materials. In addition, it is found that the size of the MWCNT stripe as well as the electrical property of the resulting anisotropic conductive thin film can be well-controlled by the gap of the shear cell.