Chlorine-35 Solid-State NMR Spectroscopy as an Indirect Probe of Germanium Oxidation State and Coordination Environment in Germanium Chlorides

Due to the prevalence of Ge–Cl bonds in germanium chemistry and the inherent challenges of germanium-73 NMR spectroscopy, chlorine-35 NMR spectroscopy was investigated as an indirect method of characterization for these ubiquitous and useful compounds. Chlorine-35 NMR parameters were correlated with...

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Published inInorganic chemistry Vol. 53; no. 14; pp. 7377 - 7388
Main Authors Hanson, Margaret A, Terskikh, Victor V, Baines, Kim M, Huang, Yining
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 21.07.2014
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Summary:Due to the prevalence of Ge–Cl bonds in germanium chemistry and the inherent challenges of germanium-73 NMR spectroscopy, chlorine-35 NMR spectroscopy was investigated as an indirect method of characterization for these ubiquitous and useful compounds. Chlorine-35 NMR parameters were correlated with structural metrics as well as the oxidation state of germanium.
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic500728w