Arylation of Diorganochalcogen Compounds with Diaryliodonium Triflates: Metal Catalysts Are Unnecessary

Diaryliodonium triflates transfer an aryl group to the chalcogen atom of organic sulfides, selenides, and tellurides (but not ethers), in the absence of transition-metal catalyst, simply upon heating in chloroform or dichloroethane solution.

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Bibliographic Details
Published inOrganic letters Vol. 16; no. 24; pp. 6382 - 6385
Main Authors Racicot, Léanne, Kasahara, Takahito, Ciufolini, Marco A.
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 19.12.2014
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
REAGENTS
SULFIDES
ACIDS
METHYL TRANSFERS
BOROFLUORIDE
TRIARYLSULFONIUM
TRIPHENYLPHOSPHINE
SALTS
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Summary:Diaryliodonium triflates transfer an aryl group to the chalcogen atom of organic sulfides, selenides, and tellurides (but not ethers), in the absence of transition-metal catalyst, simply upon heating in chloroform or dichloroethane solution.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol503177q