Facile Base-Mediated Redox Transformation: An Efficient Strategy for the Synthesis of α‑Acyloxyphosphoryl Compounds

An efficient one-pot synthesis of α-acyloxyphosphoryl compounds from aldehydes and hydrogen phosphoryl compounds has been developed using a facile base-mediated redox strategy. This redox transformation is applicable to synthesize a wide range of valuable α-acyloxyphosphoryl compounds with high atom...

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Published inOrganic letters Vol. 16; no. 23; pp. 6152 - 6155
Main Authors Zhao, Yalei, Chen, Tieqiao, Han, Daoqing, Zhao, Chang-Qiu, Han, Li-Biao
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 05.12.2014
Amer Chemical Soc
Subjects
Catalysis
Chemistry
Chemistry, Organic
Combinatorial Chemistry Techniques
Molecular Structure
Organophosphorus Compounds - chemical synthesis
Organophosphorus Compounds - chemistry
Oxidation-Reduction
Physical Sciences
Science & Technology
Stereoisomerism
SATURATED ESTERS
ACID
ATOM ECONOMY
ALPHA,BETA-UNSATURATED ALDEHYDES
ORGANOCATALYSIS
ACTIVATED CARBOXYLATES
N-HETEROCYCLIC CARBENES
HYDROXY PHOSPHONATES
ENANTIOSELECTIVE HYDROPHOSPHONYLATION
CATALYTIC GENERATION
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Summary:An efficient one-pot synthesis of α-acyloxyphosphoryl compounds from aldehydes and hydrogen phosphoryl compounds has been developed using a facile base-mediated redox strategy. This redox transformation is applicable to synthesize a wide range of valuable α-acyloxyphosphoryl compounds with high atom- and step-economic efficiency.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol503014f