MOFs as Adsorbents for Low Temperature Heating and Cooling Applications

• Published in: Journal of the American Chemical Society Vol. 131; no. 8; pp. 2776 - 2777
• Main Authors: Henninger, Stefan K, Habib, Hesham A, Janiak, Christoph
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 04.03.2009

The 3D metal−organic framework (MOF) 3 ∞{[Ni3(μ3-btc)2(μ4-btre)2(μ-H2O)2]·∼22H2O} is found to be a reversibly dehydratable−hydratable water-stable MOF material with a large loading spread of 210 g/kg as a candidate for solid adsorbents in heat transformation cycles for refrigeration, heat pumping, a...