MOFs as Adsorbents for Low Temperature Heating and Cooling Applications

The 3D metal−organic framework (MOF) 3 ∞{[Ni3(μ3-btc)2(μ4-btre)2(μ-H2O)2]·∼22H2O} is found to be a reversibly dehydratable−hydratable water-stable MOF material with a large loading spread of 210 g/kg as a candidate for solid adsorbents in heat transformation cycles for refrigeration, heat pumping, a...

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Published inJournal of the American Chemical Society Vol. 131; no. 8; pp. 2776 - 2777
Main Authors Henninger, Stefan K, Habib, Hesham A, Janiak, Christoph
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 04.03.2009
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Summary:The 3D metal−organic framework (MOF) 3 ∞{[Ni3(μ3-btc)2(μ4-btre)2(μ-H2O)2]·∼22H2O} is found to be a reversibly dehydratable−hydratable water-stable MOF material with a large loading spread of 210 g/kg as a candidate for solid adsorbents in heat transformation cycles for refrigeration, heat pumping, and heat storage.
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ISSN:0002-7863
1520-5126
1520-5126
DOI:10.1021/ja808444z