Triphenylene-Fused Porphyrins

Triphenylene has been successfully fused to the porphyrin periphery through a convenient oxidative ring-closure reaction. Bistriphenylene-fused porphyrins and a dibenzo[fg,op]tetracene-fused porphyrin have also been obtained using a similar approach. These π-extended porphyrins exhibited broadened a...

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Bibliographic Details
Published inOrganic letters Vol. 13; no. 12; pp. 3020 - 3023
Main Authors Jiang, Lin, Engle, James T, Sirk, Laura, Hartley, C. Scott, Ziegler, Christopher J, Wang, Hong
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 17.06.2011
Amer Chemical Soc
Subjects
Catalysis
Chemistry
Chemistry, Organic
Chrysenes - chemical synthesis
Chrysenes - chemistry
Models, Molecular
Molecular Structure
Palladium - chemistry
Physical Sciences
Porphyrins - chemical synthesis
Porphyrins - chemistry
Science & Technology
Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
CYCLOADDITION REACTIONS
BENZOPORPHYRINS
ABSORPTION
TAPES
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Summary:Triphenylene has been successfully fused to the porphyrin periphery through a convenient oxidative ring-closure reaction. Bistriphenylene-fused porphyrins and a dibenzo[fg,op]tetracene-fused porphyrin have also been obtained using a similar approach. These π-extended porphyrins exhibited broadened and bathochromic shifted UV–vis absorptions.
Bibliography:National Science Foundation
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol200853g