Precision Velocity Measurements of Pulsed Supersonic Jets

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 115; no. 25; pp. 6997 - 7004
• Main Authors: Christen, Wolfgang, Krause, Tim, Kobin, Björn, Rademann, Klaus
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 30.06.2011
• ISSN: 1089-5639; 1520-5215
• DOI: 10.1021/jp112222g

We introduce a straightforward experimental approach for determining the mean flow velocity of a supersonic jet with very high precision. While time measurements easily can achieve accuracies of Δt/t ≤ 10−4, typically the absolute flight distances are much less well-defined. This causes significantly increased errors in calculations of the mean flow velocity and mean kinetic energy. The basic concept to improve on this situation is changing the flight distance in vacuo by precisely defined increments employing a linear translation stage. We demonstrate the performance of this method with a flight path that can be varied by approximately 15% with a tolerance of setting of 50 μm. In doing so, an unprecedented accurate value for the mean flow velocity of Δv/⟨v⟩ < 3 × 10−4 has been obtained without prior knowledge of the total distance. This very high precision in source pressure, temperature, and particle speed facilitates an improved energetic analysis of condensation processes in supersonic jet expansions. The technique is also of broad interest to other fields employing the strong adiabatic cooling of supersonic beams, in particular, molecular spectroscopy. In the presented case study, a thorough analysis of arrival time spectra of neutral helium implies cluster formation even at elevated temperatures.