Pd-Catalyzed C−H Functionalizations of O-Methyl Oximes with Arylboronic Acids

Useful methods have been developed to construct ortho-arylated aryl aldoximes, aryl ketoximes, and fluorenones via Pd(II)-catalyzed direct C−H arylation by using arylboronic acids as arylating reagents based on the analysis of the pathways of direct functionalization of aryl aldoximes.

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Bibliographic Details
Published inOrganic letters Vol. 12; no. 1; pp. 184 - 187
Main Authors Sun, Chang-Liang, Liu, Na, Li, Bi-Jie, Yu, Da-Gang, Wang, Yang, Shi, Zhang-Jie
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 01.01.2010
Amer Chemical Soc
Subjects
Boronic Acids - chemistry
Catalysis
Chemistry
Chemistry, Organic
Molecular Structure
Oximes - chemistry
Palladium - chemistry
Physical Sciences
Science & Technology
ORGANIC-SYNTHESIS
KETONES
FLUORENONES
ACTIVATION
DIRECT ARYLATION
OXIDATIVE FUNCTIONALIZATION
COUPLING REACTIONS
CARBON-HYDROGEN BONDS
DERIVATIVES
ARYL CHLORIDES
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Summary:Useful methods have been developed to construct ortho-arylated aryl aldoximes, aryl ketoximes, and fluorenones via Pd(II)-catalyzed direct C−H arylation by using arylboronic acids as arylating reagents based on the analysis of the pathways of direct functionalization of aryl aldoximes.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol902552v