Silver-Catalyzed Imination of Sulfoxides and Sulfides

Silver salts in the presence of a chelating ligand efficiently catalyze the stereospecific imination of sulfoxides and sulfides with sulfonylamides and PhI(OAc)2 to afford sulfoximines and sulfilimines, respectively, in good yields.

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Bibliographic Details
Published inOrganic letters Vol. 7; no. 22; pp. 4983 - 4985
Main Authors Cho, Gae Young, Bolm, Carsten
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 27.10.2005
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
NITRENE TRANSFER
SULFOXIMINES
LIGANDS
MECHANISM
RU(SALEN)-CATALYZED ASYMMETRIC SULFIMIDATION
PSEUDOPEPTIDES
EFFICIENT
DERIVATIVES
N-ALKOXYCARBONYL AZIDE
IMIDATION
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Summary:Silver salts in the presence of a chelating ligand efficiently catalyze the stereospecific imination of sulfoxides and sulfides with sulfonylamides and PhI(OAc)2 to afford sulfoximines and sulfilimines, respectively, in good yields.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol0519442