A Catalyst for Efficient and Highly Enantioselective Hydrogenation of Aromatic, Heteroaromatic, and α,β-Unsaturated Ketones

PhanePhos−ruthenium−diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and α,β-unsaturated ketones with high activity and excellent enantioselectivity.

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Bibliographic Details
Published inOrganic letters Vol. 2; no. 26; pp. 4173 - 4176
Main Authors Burk, Mark J, Hems, William, Herzberg, Daniela, Malan, Christophe, Zanotti-Gerosa, Antonio
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 28.12.2000
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ALCOHOLS
ASYMMETRIC TRANSFER HYDROGENATION
HYDROBORATION
RHODIUM
REDUCTION
LIGANDS
COMPLEXES
STEREOSELECTIVE HYDROGENATION
BORANE
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Summary:PhanePhos−ruthenium−diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and α,β-unsaturated ketones with high activity and excellent enantioselectivity.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol000309n