Reaction of Benzoylnitrene with Anions:  Formation of an Intermediate in the Hofmann Rearrangement

Nucleophilic anions react rapidly with benzoylnitrene to form a species involved in the Hofmann rearrangement. This species has been detected by time-resolved infrared spectroscopy.

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Bibliographic Details
Published inOrganic letters Vol. 7; no. 24; pp. 5385 - 5387
Main Authors Mandel, Sarah M, Platz, Matthew S
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 24.11.2005
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Summary:Nucleophilic anions react rapidly with benzoylnitrene to form a species involved in the Hofmann rearrangement. This species has been detected by time-resolved infrared spectroscopy.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol051985y