Preparation of Functionalized Alkylmagnesium Derivatives Using an I/Mg-Exchange

Functionalized alkylmagnesium reagents bearing an acetal, a ketal, an ester, or a pyridine ring were prepared by an I/Mg-exchange using iPr2Mg·LiCl or ClMg(CH2)5MgCl·2LiCl starting from functionalized primary alkyl iodides.

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Bibliographic Details
Published inOrganic letters Vol. 10; no. 6; pp. 1187 - 1189
Main Authors Rauhut, Christian B, Vu, Viet Anh, Fleming, Fraser F, Knochel, Paul
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 20.03.2008
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
KETONES
BR/MG EXCHANGE
REAGENTS
MAGNESIUM EXCHANGE
RING
ESTERS
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Summary:Functionalized alkylmagnesium reagents bearing an acetal, a ketal, an ester, or a pyridine ring were prepared by an I/Mg-exchange using iPr2Mg·LiCl or ClMg(CH2)5MgCl·2LiCl starting from functionalized primary alkyl iodides.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol8000987