Iron-Catalyzed Imination of Sulfoxides and Sulfides

The Fe(III)-catalyzed imination of sulfoxides and sulfides with sulfonylamides in the presence of iodinanes has been investigated. The best results were obtained when Fe(acac)3 was used as a catalyst in combination with iodosylbenzene, providing an effective alternative (stereospecific) access to su...

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Bibliographic Details
Published inOrganic letters Vol. 8; no. 11; pp. 2349 - 2352
Main Authors Mancheño, Olga García, Bolm, Carsten
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 25.05.2006
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
OXIDATION
NITRENE TRANSFER
SULFOXIMINES
LIGANDS
RU(SALEN)-CATALYZED ASYMMETRIC SULFIMIDATION
C-1-SYMMETRIC AMINOSULFOXIMINES
PSEUDOPEPTIDES
EFFICIENT
N-ALKOXYCARBONYL AZIDE
IMIDATION
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Summary:The Fe(III)-catalyzed imination of sulfoxides and sulfides with sulfonylamides in the presence of iodinanes has been investigated. The best results were obtained when Fe(acac)3 was used as a catalyst in combination with iodosylbenzene, providing an effective alternative (stereospecific) access to sulfoximines and sulfilimines.
Bibliography:ObjectType-Article-1
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol060640s