Enantioselective cyclopropane syntheses using the chiral carbene complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe:CHCH3+. A mechanistic analysis of the carbene transfer reaction

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 113; no. 3; pp. 927 - 939
Main Authors Brookhart, Maurice, Liu, Yumin, Goldman, Emma W, Timmers, Debra A, Williams, Gregory D
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.01.1991
Subjects
Chemical reactivity
Chemistry
Exact sciences and technology
Organic chemistry
Reactivity and mechanisms
Cationic complex
Enantioselectivity
Hydrocarbon
Organic ligand
Transition metal Carbonyl Complexes
Enol ester
Cyclopropanation
Iron Organic compounds
Carbene
Iron Carbonyl Complexes
Transfer reaction
Reaction mechanism
Benzenic compound
Hapto complex
Ethylenic compound
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Bibliography:istex:30CFB9DB5B0277BB15D15F948680026BA2B3F5AE
ark:/67375/TPS-BPLQ8X0G-F
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00003a028