Photocatalytic Cross-Coupling of Tetrafluoropyridine Sulfides with Vinyl Halides for the Synthesis of β,γ-Unsaturated Carbonyl Compounds

β,γ-Unsaturated carbonyl compounds serve as versatile building blocks in organic synthesis and medicinal chemistry. Herein we reported the synthesis of β,γ-unsaturated carbonyl compounds from tetrafluoropyridine sulfides with vinyl halides. This cross-coupling reaction takes the advantage of photoca...

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Bibliographic Details
Published inJournal of organic chemistry Vol. 88; no. 22; pp. 15761 - 15766
Main Authors Zaman, Muhammad Kashif, Li, Ruining, Deng, Wei
Format Journal Article
LanguageEnglish
Published American Chemical Society 17.11.2023
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Summary:β,γ-Unsaturated carbonyl compounds serve as versatile building blocks in organic synthesis and medicinal chemistry. Herein we reported the synthesis of β,γ-unsaturated carbonyl compounds from tetrafluoropyridine sulfides with vinyl halides. This cross-coupling reaction takes the advantage of photocatalysis, as well as zinc catalysis, which is preferred due to its less-toxic, earth abundant, and cost-effective nature.
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content type line 23
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.3c01800