Cu(I)-Catalyzed Intermolecular Diamination of Activated Terminal Olefins
This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions.
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| Published in | Organic letters Vol. 9; no. 24; pp. 4943 - 4945 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
WASHINGTON
American Chemical Society
22.11.2007
Amer Chemical Soc |
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| Online Access | Get full text |
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| Abstract | This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions. |
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| AbstractList | This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions. This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions.This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions. |
| Author | Yuan, Weicheng Zhao, Baoguo Du, Haifeng Shi, Yian |
| Author_xml | – sequence: 1 givenname: Baoguo surname: Zhao fullname: Zhao, Baoguo – sequence: 2 givenname: Weicheng surname: Yuan fullname: Yuan, Weicheng – sequence: 3 givenname: Haifeng surname: Du fullname: Du, Haifeng – sequence: 4 givenname: Yian surname: Shi fullname: Shi, Yian |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/17973481$$D View this record in MEDLINE/PubMed |
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| Keywords | ORGANIC-SYNTHESIS PROMOTED INTRAMOLECULAR DIAMINATION ELECTROPHILIC DIAMINATION RADICAL CYCLIZATION CONJUGATED DIENES COMPLEXES BISINDOLE ALKALOIDS ALKENYL OXAZIRIDINES VICINAL DIAMINATION 1,2-DIAMINATION |
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| Snippet | This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A... |
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| SubjectTerms | Alkenes - chemistry Amination Catalysis Chemistry Chemistry, Organic Copper - chemistry Crystallography, X-Ray Diamines - chemical synthesis Diamines - chemistry Models, Molecular Molecular Structure Physical Sciences Science & Technology Stereoisomerism |
| Title | Cu(I)-Catalyzed Intermolecular Diamination of Activated Terminal Olefins |
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