Cu(I)-Catalyzed Intermolecular Diamination of Activated Terminal Olefins

This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions.

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Bibliographic Details
Published inOrganic letters Vol. 9; no. 24; pp. 4943 - 4945
Main Authors Zhao, Baoguo, Yuan, Weicheng, Du, Haifeng, Shi, Yian
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 22.11.2007
Amer Chemical Soc
Subjects
Alkenes - chemistry
Amination
Catalysis
Chemistry
Chemistry, Organic
Copper - chemistry
Crystallography, X-Ray
Diamines - chemical synthesis
Diamines - chemistry
Models, Molecular
Molecular Structure
Physical Sciences
Science & Technology
Stereoisomerism
ORGANIC-SYNTHESIS
PROMOTED INTRAMOLECULAR DIAMINATION
ELECTROPHILIC DIAMINATION
RADICAL CYCLIZATION
CONJUGATED DIENES
COMPLEXES
BISINDOLE ALKALOIDS
ALKENYL OXAZIRIDINES
VICINAL DIAMINATION
1,2-DIAMINATION
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Summary:This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol702061s