Effect of Structure and Size on the Electrical Properties of Nanocrystalline WO3 Films

• Published in: ACS applied materials & interfaces Vol. 2; no. 9; pp. 2623 - 2628
• Main Authors: Vemuri, R.S, Bharathi, K. Kamala, Gullapalli, S.K, Ramana, C.V
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 01.09.2010
• Subjects: Electric Conductivity; Materials Testing; Membranes, Artificial; Nanostructures - chemistry; Nanostructures - ultrastructure; Oxides - chemistry; Particle Size; Tungsten - chemistry; H2S sensors; WO3 thin films; variable range hopping; size effects; small polaron hopping; electrical properties
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/am1004514

Nanocrystalline WO3 films were grown by reactive magnetron sputter-deposition by varying the substrate temperature in the range of 303(RT)−673 K. The structure and electrical transport properties of WO3 films were evaluated using X-ray diffraction and dc electrical conductivity measurements. The effect of ultramicrostructure and grain-size was significant on the electrical properties of WO3 films. DC conductivity variation of the WO3 films measured in the temperature range of 120−300 K reveals their semiconducting nature. The temperature dependent electrical conductivity curves exhibit two distinct regions indicative of two different types of electrical transport mechanisms. Analysis of the conductivity indicates that the small polaron and variable-range-hopping mechanisms are operative in 180−300 K and 120−180 K temperature regions, respectively. The density of localized states at the Fermi level, N(E F), has been calculated and it was found to be ∼1 × 1019 eV−1 cm−3 for all the films.