Selective Lithiation–Expansion–Microexplosion Synthesis of Two-Dimensional Fluoride-Free Mxene

• Published in: ACS materials letters Vol. 1; no. 6; pp. 628 - 632
• Main Authors: Sun, Zemin, Yuan, Mengwei, Lin, Liu, Yang, Han, Nan, Caiyun, Li, Huifeng, Sun, Genban, Yang, Xiaojing
• Format: Journal Article
• Language: English
• Published: American Chemical Society 02.12.2019
• ISSN: 2639-4979; 2639-4979
• DOI: 10.1021/acsmaterialslett.9b00390

Two-dimensional MXene, a significant member of the two-dimensional family, has attracted much interest in physics, energy evolution, environmental science, and nanomedicine. However, the acute toxicity of fluoride-based synthetic procedures remains an impediment to large-scale fabrication and applications. It is an urgent need to develop an innocuous and effective protocol for MXene synthesis. Therefore, we developed a facile, rapid fluoride-free electrochemical etching strategy based on the selective corrosion of Al layers in titanium aluminum carbide (Ti3AlC2) in a traditional Li-ion battery system. On the basis of the intercalation–alloying–expansion–microexplosion mechanism, single- and few-layer fluoride-free Ti3C2T x (T = O or OH) were prepared. Furthermore, the fluoride-free Ti3C2T x exhibits excellent capability for a supercapacitor. This strategy provides a safe, green, and environmentally friendly way to realize the production of ultrathin MXene materials from MAX.