A Versatile Preparative Route to 5-Substituted-1,10-Phenanthroline Ligands via 1,10-Phenanthroline 5,6-Epoxide

The reactive ligand 1,10-phenanthroline-5,6-epoxide is a versatile starting material for the preparation of a variety of 5-substituted-1, 10-phenanthroline ligands by reaction with oxygen-, carbon-, or nitrogen-based nucleophiles. All of the new ligands readily form complexes with the fac-Re-1(CO)(3...

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Bibliographic Details
Published inInorganic chemistry Vol. 34; no. 25; pp. 6235 - 6236
Main Authors Shen, Yibing, Sullivan, B. Patrick
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 01.12.1995
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Physical Sciences
Science & Technology
OXIDATION
CROWN
PERSPECTIVES
COMPLEXES
SUPRAMOLECULAR CHEMISTRY
PHENANTHROLINES
CATALYSTS
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Summary:The reactive ligand 1,10-phenanthroline-5,6-epoxide is a versatile starting material for the preparation of a variety of 5-substituted-1, 10-phenanthroline ligands by reaction with oxygen-, carbon-, or nitrogen-based nucleophiles. All of the new ligands readily form complexes with the fac-Re-1(CO)(3)Cl fragment. Of particular interest are the syntheses of the amino and aminocrown derivatives of Re-1 which can function as cation sensors by perturbation of molecular luminescence. An interesting example involving Pb2+ is presented.
Bibliography:istex:9FCA3BE7B6D83E0D10B963419EF43415FF9E3A6D
ark:/67375/TPS-7Q87TLDN-3
ISSN:0020-1669
1520-510X
DOI:10.1021/ic00129a003