Green Synthesis of Pseudocoherent Fluoride Cathode Materials from Wastes

Due to fluorine’s high electronegativity, which facilitates the highest discharge plateau and exceptional energy density, transition metal fluorides (TMFs) are considered one of the most promising cathode materials for lithium-ion batteries. However, the complexity and toxicity of the synthesis proc...

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Published inNano letters Vol. 25; no. 24; pp. 9543 - 9550
Main Authors Ma, Yue, Zhao, Yingnan, Zhou, Xianggang, Li, Yingqi, Gu, Ruiqian, Li, Yumeng, Yao, Rui-Qi, Shi, Hang, Wang, Tong-Hui, Han, Gao-Feng, Lang, Xing-You, Jiang, Qing
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 18.06.2025
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Abstract Due to fluorine’s high electronegativity, which facilitates the highest discharge plateau and exceptional energy density, transition metal fluorides (TMFs) are considered one of the most promising cathode materials for lithium-ion batteries. However, the complexity and toxicity of the synthesis process as well as the durability of TMFs hinder their wide application. Herein, we present a green synthesis strategy of iron fluorides (FeF x ), utilizing recycled polytetrafluoroethylene as fluorine source, combined with Fe powder through mechanochemical ball-milling at ambient conditions (35 °C). Benefiting from the coupling reaction between pseudocoherent FeF x and semi-ionic CF y , the resulting FeF x -CF y cathode delivers an impressive capacity of 240.0 mAh g–1 and maintains 76.2% after 2000 cycles at 1C, obviously surpassing the prevailing LiNi0.8Co0.1Mn0.1O2 and LiFePO4 cathodes. This work not only introduces a sustainable strategy for synthesizing high-performance and high value-added fluorides under mild conditions but also contributes to waste recycling.
AbstractList Due to fluorine's high electronegativity, which facilitates the highest discharge plateau and exceptional energy density, transition metal fluorides (TMFs) are considered one of the most promising cathode materials for lithium-ion batteries. However, the complexity and toxicity of the synthesis process as well as the durability of TMFs hinder their wide application. Herein, we present a green synthesis strategy of iron fluorides (FeF ), utilizing recycled polytetrafluoroethylene as fluorine source, combined with Fe powder through mechanochemical ball-milling at ambient conditions (35 °C). Benefiting from the coupling reaction between pseudocoherent FeF and semi-ionic CF , the resulting FeF -CF cathode delivers an impressive capacity of 240.0 mAh g and maintains 76.2% after 2000 cycles at 1C, obviously surpassing the prevailing LiNi Co Mn O and LiFePO cathodes. This work not only introduces a sustainable strategy for synthesizing high-performance and high value-added fluorides under mild conditions but also contributes to waste recycling.
Due to fluorine’s high electronegativity, which facilitates the highest discharge plateau and exceptional energy density, transition metal fluorides (TMFs) are considered one of the most promising cathode materials for lithium-ion batteries. However, the complexity and toxicity of the synthesis process as well as the durability of TMFs hinder their wide application. Herein, we present a green synthesis strategy of iron fluorides (FeF x ), utilizing recycled polytetrafluoroethylene as fluorine source, combined with Fe powder through mechanochemical ball-milling at ambient conditions (35 °C). Benefiting from the coupling reaction between pseudocoherent FeF x and semi-ionic CF y , the resulting FeF x -CF y cathode delivers an impressive capacity of 240.0 mAh g–1 and maintains 76.2% after 2000 cycles at 1C, obviously surpassing the prevailing LiNi0.8Co0.1Mn0.1O2 and LiFePO4 cathodes. This work not only introduces a sustainable strategy for synthesizing high-performance and high value-added fluorides under mild conditions but also contributes to waste recycling.
Due to fluorine's high electronegativity, which facilitates the highest discharge plateau and exceptional energy density, transition metal fluorides (TMFs) are considered one of the most promising cathode materials for lithium-ion batteries. However, the complexity and toxicity of the synthesis process as well as the durability of TMFs hinder their wide application. Herein, we present a green synthesis strategy of iron fluorides (FeFx), utilizing recycled polytetrafluoroethylene as fluorine source, combined with Fe powder through mechanochemical ball-milling at ambient conditions (35 °C). Benefiting from the coupling reaction between pseudocoherent FeFx and semi-ionic CFy, the resulting FeFx-CFy cathode delivers an impressive capacity of 240.0 mAh g-1 and maintains 76.2% after 2000 cycles at 1C, obviously surpassing the prevailing LiNi0.8Co0.1Mn0.1O2 and LiFePO4 cathodes. This work not only introduces a sustainable strategy for synthesizing high-performance and high value-added fluorides under mild conditions but also contributes to waste recycling.Due to fluorine's high electronegativity, which facilitates the highest discharge plateau and exceptional energy density, transition metal fluorides (TMFs) are considered one of the most promising cathode materials for lithium-ion batteries. However, the complexity and toxicity of the synthesis process as well as the durability of TMFs hinder their wide application. Herein, we present a green synthesis strategy of iron fluorides (FeFx), utilizing recycled polytetrafluoroethylene as fluorine source, combined with Fe powder through mechanochemical ball-milling at ambient conditions (35 °C). Benefiting from the coupling reaction between pseudocoherent FeFx and semi-ionic CFy, the resulting FeFx-CFy cathode delivers an impressive capacity of 240.0 mAh g-1 and maintains 76.2% after 2000 cycles at 1C, obviously surpassing the prevailing LiNi0.8Co0.1Mn0.1O2 and LiFePO4 cathodes. This work not only introduces a sustainable strategy for synthesizing high-performance and high value-added fluorides under mild conditions but also contributes to waste recycling.
Author Ma, Yue
Gu, Ruiqian
Yao, Rui-Qi
Lang, Xing-You
Li, Yumeng
Li, Yingqi
Shi, Hang
Han, Gao-Feng
Jiang, Qing
Zhao, Yingnan
Zhou, Xianggang
Wang, Tong-Hui
AuthorAffiliation Key Laboratory of Polyoxometalate and Reticular Material Chemistry, Ministry of Education, Faculty of Chemistry
Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, and School of Materials Science and Engineering
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  givenname: Xing-You
  orcidid: 0000-0002-8227-9695
  surname: Lang
  fullname: Lang, Xing-You
  email: xylang@jlu.edu.cn
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  givenname: Qing
  orcidid: 0000-0003-0660-596X
  surname: Jiang
  fullname: Jiang, Qing
  email: jiangq@jlu.edu.cn
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lithium-ion batteries
green synthesis
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Snippet Due to fluorine’s high electronegativity, which facilitates the highest discharge plateau and exceptional energy density, transition metal fluorides (TMFs) are...
Due to fluorine's high electronegativity, which facilitates the highest discharge plateau and exceptional energy density, transition metal fluorides (TMFs) are...
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Title Green Synthesis of Pseudocoherent Fluoride Cathode Materials from Wastes
URI http://dx.doi.org/10.1021/acs.nanolett.5c00489
https://www.ncbi.nlm.nih.gov/pubmed/40470920
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Volume 25
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