Monomeric Silver(I) β-Diketiminate Complexes

New silver(I) β-diketiminate complexes have been prepared and characterized. Monomeric complexes with ethylene (4), triphenylphosphine (5), and IMes (IMes =1,3-dimesitylimidazol-2-ylidene) (8) as well as a dinuclear acetonitrile complex (3) were characterized by 1H NMR, 13C NMR, elemental analysis,...

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Bibliographic Details
Published inOrganometallics Vol. 25; no. 17; pp. 4054 - 4057
Main Authors Chiong, Hendrich A, Daugulis, Olafs
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 14.08.2006
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
POLYMERS
INSERTION
ACTIVATION
CARBENE SILVER(I)
CHEMISTRY
LIGAND
EFFICIENT
SALTS
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Summary:New silver(I) β-diketiminate complexes have been prepared and characterized. Monomeric complexes with ethylene (4), triphenylphosphine (5), and IMes (IMes =1,3-dimesitylimidazol-2-ylidene) (8) as well as a dinuclear acetonitrile complex (3) were characterized by 1H NMR, 13C NMR, elemental analysis, and X-ray crystallography. These complexes are stable in the solid state at ambient temperature and inert atmosphere.
Bibliography:istex:431B297A84C4652DCF9463F2AC1771251289228D
ark:/67375/TPS-JTM52R8C-L
ISSN:0276-7333
1520-6041
DOI:10.1021/om0603621