1,2-Carbastanna-closo-dodecaborate, a New Tin Ligand in Coordination Chemistry:  Synthesis, Structure, and Reactivity

The synthesis of [MePPh3][SnCB10H11] is presented together with its structural, NMR, and 119Sn Mössbauer spectroscopical characterization. Two transition metal complexes, [Au4(PPh3)4(SnCB10H11)2] and [Bu4N]2[Rh(PPh3)2(SnCB10H11)3], with the carbastannaborate coordinated at rhodium or gold via the ti...

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Published inOrganometallics Vol. 26; no. 23; pp. 5696 - 5701
Main Authors Joosten, Dominik, Weissinger, Ines, Kirchmann, Marius, Maichle-Mössmer, Cäcilia, Schappacher, Falko M, Pöttgen, Rainer, Wesemann, Lars
Format Journal Article
LanguageEnglish
Published American Chemical Society 05.11.2007
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Summary:The synthesis of [MePPh3][SnCB10H11] is presented together with its structural, NMR, and 119Sn Mössbauer spectroscopical characterization. Two transition metal complexes, [Au4(PPh3)4(SnCB10H11)2] and [Bu4N]2[Rh(PPh3)2(SnCB10H11)3], with the carbastannaborate coordinated at rhodium or gold via the tin atom are presented, and the structural and NMR spectroscopical data are discussed.
Bibliography:istex:F23BB2FB548C73F55F56AE237E45802AEB644B13
ark:/67375/TPS-S20P8N18-V
ISSN:0276-7333
1520-6041
DOI:10.1021/om7006858