Correlating Molecular Structure to Field-Effect Mobility: The Investigation of Side-Chain Functionality in Phenylene−Thiophene Oligomers and Their Application in Field Effect Transistors
Short conjugated phenylene (P)−thiophene (T) oligomers with varying α and ω alkyl and alkoxy substitutions were synthesized using Stille and Suzuki coupling reactions to investigate the correlation between end-group structure and electronic properties on P2TP and P3TP conjugated cores. Several solub...
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Published in | Chemistry of materials Vol. 19; no. 9; pp. 2342 - 2351 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
01.05.2007
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Online Access | Get full text |
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Summary: | Short conjugated phenylene (P)−thiophene (T) oligomers with varying α and ω alkyl and alkoxy substitutions were synthesized using Stille and Suzuki coupling reactions to investigate the correlation between end-group structure and electronic properties on P2TP and P3TP conjugated cores. Several soluble oligomers were synthesized with 5,5‘-bis(4-n-octylphenyl)-2,2‘-bithiophene (do-PTTP) showing the highest mobility (μ = 0.18 cm2 V-1 s-1) and on/off ratio of 107 at a substrate temperature of 50 °C. Thin film morphologies analyzed using atomic force microscopy revealed higher nucleation densities for branched alkoxy side-chain molecules compared to those of their straight alkyl side-chain counterparts. Field-effect mobility showed an inverse correlation to side-group bulkiness, indicating a strong morphological component to charge transport in the P2TP and P3TP series. |
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Bibliography: | ark:/67375/TPS-5FDQ5RB9-R istex:E6E5953FB3C02E462948F20F761C188D4D1C0F8E |
ISSN: | 0897-4756 1520-5002 |
DOI: | 10.1021/cm070117n |